Ultrafast coherent oscillations reveal a reactive mode in the ring-opening reaction of fulgides
Slavov, C.; Bellakbil, Nabil; Wahl, J.; Mayer, Kerstin; Rück-Braun, Karola; Burghardt, I.; Wachtveitl, Josef; Braun, M.
The ultrafast ring-opening reaction of photochromic fulgides proceeds via conical intersections to the ground state isomers involving activation barriers in the excited state. The coherent oscillations observed in the femtosecond transient absorption signal of a methyl-substituted indolylfulgide were analysed in the framework of vibrational wavepackets to expose a dominant low-frequency mode at similar to 80 cm(-1). The quantum chemical calculations in the relaxed excited state geometry of this fulgide revealed that the experimentally observed vibrational normal mode has a dominant contribution to the relevant ring-opening reactive coordinate.
