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Surface enhanced resonance Raman detection of a catalytic intermediate of DyP-type peroxidase

Todorovic, Smilja; Hildebrandt, Peter; Martins, Ligia O.

We report herein the vibrational spectroscopic characterisation of a catalytic intermediate formed by the reaction of H2O2 with DyP-type peroxidase immobilised on a biocompatible coated metal support. The SERR spectroscopic approach is of general applicability to other peroxidases which form relatively stable catalytic intermediates.
Published in: Physical chemistry, chemical physics, 10.1039/c5cp01283j, Royal Society of Chemistry
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  • This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.