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Microporous polymer network films covalently bound to gold electrodes

Becker, Daniel; Heidary, Nina; Horch, Marius; Gernert, Ulrich; Zebger, Ingo; Schmidt, Johannes; Fischer, Anna; Thomas, Arne

Covalent attachment of a microporous polymer network (MPN) on a gold surface is presented. A functional bromophenyl-based self-assembled monolayer (SAM) formed on the gold surface acts as co-monomer in the polymerisation of the MPN yielding homogeneous and robust coatings. Covalent binding of the films to the electrode is confirmed by SEIRAS measurements.
Published in: Chemical communications, 10.1039/c4cc09637a, Royal Society of Chemistry
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