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Irreversibility and Second Law

Muschik, Wolfgang

According to M. Eigen there are two reasons for irreversibility: weak and strict temporality. Measures for irreversibility are defined by different formulations of the 2nd law which can be divided into two classes: the more general in time integrated formulations as Clausius' inequality and the more special in time local formulations as the non-negativity of the entropy production density. The logical relations between eight different formulations of the 2nd law are investigated and discussed.
Published in: Journal of non-equilibrium thermodynamics, 10.1515/jnet.1998.23.1.87, De Gruyter
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  • This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.