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🆕 Date Issued:
1988
🗄 In DepositOnce:2019-01-02
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MetalIocen-o-phenylenbis(phenylphosphido)-Chelate des Molybdäns und Wolframs

Köpf, Hartmut; Richtering, Verena

The reaction of the metallocene dichlorides Cp2MCl2 (Cp = η5-C5H5; M = Mo, W) with equimolar amounts of dilithium-o-phenylenebis(phenylphosphide) 1,2-(LiPPh)2C6H4 yields the five-membered chelate complexes Cp2M[1,2-(PPh)2C6H4] (M = Mo. 1; W, 2). Compounds 1 and 2 are characterized by IR, NMR and mass spectra.
metallocene complexeso-phenylenebis(phenylphosphido) chelatesbis(η5-cyclopentachenyl)-o-phenylenebis(phenylphosphane)diato-p,p'-molybdenum(IV)bis(η5-cyclopentadienyl)-o-phenylenebis(phenylphosphane)diato-p,p'-tungsten(IV)
Published in: Zeitschrift für Naturforschung B, 10.1515/znb-1988-1220, De Gruyter
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