Thumbnail Image
🆕 Date Issued:
1983
🗄 In DepositOnce:2019-01-02
Published Version

Please use this identifier to cite or link to this item:

Barrier to Rotation about Sulfur-Sulfur Bonds in Homocyclic Sulfur Molecules

Steudel, Ralf

It is shown that the distances (d) of the 19 longest bonds in 9 homocyclic sulfur rings of type Sn (n = 6-20) depend on the torsional angles (τ) which vary between 0° and 140°. The function d = f(τ) is smallest for τ = 90-100° and largest for τ = 0°; the corresponding bond distance variation amounts to 13 pm or 6%. The height of the torsional cis-barrier is estimated from the enthalpy of formation of gaseous S7 as equal to or smaller than 24 kJ/mol.
elemental sulfursulfur ringssulfur-sulfur bondstorsional barrierbond distances
Published in: Zeitschrift für Naturforschung B, 10.1515/znb-1983-0502, De Gruyter
Creative Commons Attribution NonCommercial NoDerivatives 4.0 (CC BY-NC-ND)Creative Commons Attribution NonCommercial NoDerivatives 4.0 (CC BY-NC-ND)Creative Commons Attribution NonCommercial NoDerivatives 4.0 (CC BY-NC-ND)Creative Commons Attribution NonCommercial NoDerivatives 4.0 (CC BY-NC-ND)
Full item page