Thumbnail Image
🆕 Date Issued:
1981
🗄 In DepositOnce:2019-01-04
Published Version

Please use this identifier to cite or link to this item:

Molekül- und Kristallstruktur von 1.1-Dimethylsilylentitanocendichlorid, (CH3)2Si(C5H4)2TiCl2

Köpf, Hartmut; Pickardt, Joachim

The molecular structure of the bridged [1]-titanocenophane 1,1'-dimethylsilylene titanocene dichloride, (CH3)2Si(C5H4)2TiCl2, has been investigated by an X-ray structure determination. Crystal data: monoclinic, space group C2/c, Z = 4, a = 1332.9(3), 6 = 988.7(3), c = 1068.9(3) pm, β = 113.43(2)°. The results are compared with the structural dimensions of similar compounds: 1,1'-methylene titanocene dichloride, CH2(C5H4)TiCl2, with the unbridged titanocene dichloride, (C5H5)2TiCl2 and the ethylene-bridged compound (CH2)2(C5H4)2TiCl2.
[l]-titanocenophane1,1'-dimethylsilylene titanocene dichloridemolecular structurex-ray
Published in: Zeitschrift für Naturforschung B, 10.1515/znb-1981-1002, De Gruyter
Creative Commons Attribution NonCommercial NoDerivatives 4.0 (CC BY-NC-ND)Creative Commons Attribution NonCommercial NoDerivatives 4.0 (CC BY-NC-ND)Creative Commons Attribution NonCommercial NoDerivatives 4.0 (CC BY-NC-ND)Creative Commons Attribution NonCommercial NoDerivatives 4.0 (CC BY-NC-ND)
Full item page