Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-9580
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dc.contributor.authorXiong, Yun-
dc.contributor.authorYao, Shenglai-
dc.contributor.authorSzilvási, Tibor-
dc.contributor.authorRuzicka, Ales-
dc.contributor.authorDrieß, Matthias-
dc.date.accessioned2020-01-30T11:55:00Z-
dc.date.available2020-01-30T11:55:00Z-
dc.date.issued2019-12-10-
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/10677-
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-9580-
dc.description.abstractThe unexpected reactivity of the o-carborane supported bis-silylene [(LSi:)C]2B10H101 {L= PhC(tBuN)2} towards carbon monoxide and 2,6-dimethylphenyl isocyanide is reported. While the reaction of 1 with CO leads selectively to the novel head-to-head coupling and C–O cleavage product 2 from two molecules 1 and four molecules CO, the reaction of 1 with 2,6-dimethylphenyl isocyanide affords solely the 1 : 2 molar head-to-tail coupling product 3 with a Si[double bond, length as m-dash]C bond.en
dc.description.sponsorshipTU Berlin, Open-Access-Mittel - 2019en
dc.language.isoenen
dc.rights.urihttps://creativecommons.org/licenses/by-nc/3.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.otherhomocouplingen
dc.subject.otherortho-carboraneen
dc.subject.othercarbon monoxideen
dc.subject.otherisocyanideen
dc.titleHomocoupling of CO and isocyanide mediated by a C,C′-bis(silylenyl)-substituted ortho-carboraneen
dc.typeArticleen
tub.accessrights.dnbfreeen
tub.publisher.universityorinstitutionTechnische Universität Berlinen
dc.identifier.eissn1364-548X-
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1039/C9CC08680Cen
dcterms.bibliographicCitation.journaltitleChemical Communicationsen
dcterms.bibliographicCitation.originalpublisherplaceCambridgeen
dcterms.bibliographicCitation.volume56en
dcterms.bibliographicCitation.pageend750en
dcterms.bibliographicCitation.pagestart747en
dcterms.bibliographicCitation.originalpublishernameRoyal Society of Chemistryen
dcterms.bibliographicCitation.issue5en
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