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Main Title: H2 as a fuel for flavin- and H2O2-dependent biocatalytic reactions
Author(s): Al-Shameri, Ammar
Willot, Sébastien J.-P.
Paul, Caroline E.
Hollmann, Frank
Lauterbach, Lars
Type: Article
Is Part Of: 10.14279/depositonce-10645
Language Code: en
Abstract: The soluble hydrogenase from Ralstonia eutropha provides an atom efficient regeneration system for reduced flavin cofactors using H2 as an electron source. We demonstrated this system for highly selective ene-reductase-catalyzed C[double bond, length as m-dash]C-double bond reductions and monooxygenase-catalyzed epoxidation. Reactions were expanded to aerobic conditions to supply H2O2 for peroxygenase-catalyzed hydroxylations.
Issue Date: 14-Jul-2020
Date Available: 17-Aug-2020
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): flavin
aerobic reoxidation
Sponsor/Funder: DFG, 284111627, H2-basierende Kaskaden für die Biosynthese von N-Heterocyclen
DFG, 405325648, ,Engineering von O2-toleranten Hydrogenasen und ihre physiologischen Auswirkungen in rekombinanten Bakterien im Hinblick auf die Hydrogenase-abhängige NAD(P)H-Regeneration und H2-Produktion
DFG, 390540038, EXC 2008: UniSysCat
TU Berlin, Open-Access-Mittel - 2020
Journal Title: Chemical Communications
Publisher: Royal Society of Chemistry (RSC)
Publisher Place: Cambridge
Publisher DOI: 10.1039/D0CC03229H
EISSN: 1364-548X
ISSN: 1359-7345
Appears in Collections:Inst. Chemie » Publications

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