Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-10952
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dc.contributor.authorTholen, Patrik-
dc.contributor.authorPeeples, Craig A.-
dc.contributor.authorSchaper, Raoul-
dc.contributor.authorBayraktar, Ceyda-
dc.contributor.authorErkal, Turan Selman-
dc.contributor.authorAyhan, Mehmet Menaf-
dc.contributor.authorÇoşut, Bünyemin-
dc.contributor.authorBeckmann, Jens-
dc.contributor.authorYazaydin, A. Ozgur-
dc.contributor.authorWark, Michael-
dc.contributor.authorHanna, Gabriel-
dc.contributor.authorZorlu, Yunus-
dc.contributor.authorYücesan, Gündoğ-
dc.date.accessioned2020-11-30T08:46:56Z-
dc.date.available2020-11-30T08:46:56Z-
dc.date.issued2020-06-23-
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/12078-
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-10952-
dc.description.abstractHerein, we report a semiconductive, proton-conductive, microporous hydrogen-bonded organic framework (HOF) derived from phenylphosphonic acid and 5,10,15,20‐tetrakis[p‐phenylphosphonic acid] porphyrin (GTUB5). The structure of GTUB5 was characterized using single crystal X-ray diffraction. A narrow band gap of 1.56 eV was extracted from a UV-Vis spectrum of pure GTUB5 crystals, in excellent agreement with the 1.65 eV band gap obtained from DFT calculations. The same band gap was also measured for GTUB5 in DMSO. The proton conductivity of GTUB5 was measured to be 3.00 × 10−6 S cm−1 at 75 °C and 75% relative humidity. The surface area was estimated to be 422 m2 g−1 from grand canonical Monte Carlo simulations. XRD showed that GTUB5 is thermally stable under relative humidities of up to 90% at 90 °C. These findings pave the way for a new family of organic, microporous, and semiconducting materials with high surface areas and high thermal stabilities.en
dc.description.sponsorshipDFG, 414044773, Open Access Publizieren 2019 - 2020 / Technische Universität Berlinen
dc.language.isoenen
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.othermaterials scienceen
dc.subject.otherHOFen
dc.subject.otherhydrogen-bonded organic frameworken
dc.titleSemiconductive microporous hydrogen-bonded organophosphonic acid frameworksen
dc.typeArticleen
tub.accessrights.dnbfreeen
tub.publisher.universityorinstitutionTechnische Universität Berlinen
dc.identifier.eissn2041-1723-
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1038/s41467-020-16977-0en
dcterms.bibliographicCitation.journaltitleNature Communicationsen
dcterms.bibliographicCitation.originalpublisherplaceLondonen
dcterms.bibliographicCitation.volume11en
dcterms.bibliographicCitation.originalpublishernameNature Communicationsen
dcterms.bibliographicCitation.articlenumber3180en
Appears in Collections:FG Lebensmittelchemie und Toxikologie » Publications

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