Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-11091
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dc.contributor.authorYao, Shenglai-
dc.contributor.authorSzilvási, Tibor-
dc.contributor.authorXiong, Yun-
dc.contributor.authorLorent, Christian-
dc.contributor.authorRuzicka, Ales-
dc.contributor.authorDriess, Matthias-
dc.date.accessioned2020-12-16T14:51:05Z-
dc.date.available2020-12-16T14:51:05Z-
dc.date.issued2020-09-28-
dc.identifier.issn1433-7851-
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/12216-
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-11091-
dc.description.abstractThe first series of bis(silylene)‐stabilized nitrogen(I) compounds is described. Starting from the 1,2‐bis(N‐heterocyclic silylenyl) 1,2‐dicarba‐closo‐dedocaborane(12) scaffold 1, [1,2‐(LSi)2C2B10H10; L=PhC(NtBu)2], reaction with adamantyl azide (AdN3) affords the terminal N‐μ2‐bridged zwitterionic carborane‐1,2‐bis(silylium) AdN3 adduct 2 with an open‐cage dianionic nido‐C2B10 cluster core. Remarkably, upon one‐electron reduction of 2 with C8K and liberation of N2 and adamantane, the two silylene subunits are regenerated to furnish the isolable bis(silylene)‐stabilized NI complex as an anion of 3 with the nido‐C2B10 cluster cage. On the other hand, one‐electron oxidation of 2 with silver(I) yields the monocationic bis(silylene) NI complex 4 with the closo‐C2B10 cluster core. Moreover, the corresponding neutral NI radical complex 5 results from single‐electron transfer from 3 to 4.en
dc.description.sponsorshipDFG, 390540038, EXC 2008: Unifying Systems in Catalysis "UniSysCat"en
dc.description.sponsorshipTU Berlin, Open-Access-Mittel – 2020en
dc.language.isoenen
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.otherazidesen
dc.subject.othercarboranesen
dc.subject.othernitrogen complexesen
dc.subject.otherredox non-innocent ligandsen
dc.subject.othersilylenesen
dc.titleBis(silylene)‐Stabilized Monovalent Nitrogen Complexesen
dc.typeArticleen
dc.date.updated2020-12-07T11:01:29Z-
tub.accessrights.dnbfreeen
tub.publisher.universityorinstitutionTechnische Universität Berlinen
dc.identifier.eissn1521-3773-
dc.type.versionpublishedVersionen
dcterms.bibliographicCitation.doi10.1002/anie.202011598en
dcterms.bibliographicCitation.journaltitleAngewandte Chemie International Editionen
dcterms.bibliographicCitation.originalpublisherplaceNew York, NYen
dcterms.bibliographicCitation.volume59en
dcterms.bibliographicCitation.pageend22047en
dcterms.bibliographicCitation.pagestart22043en
dcterms.bibliographicCitation.originalpublishernameWileyen
dcterms.bibliographicCitation.issue49en
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