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Main Title: Activation of the Si–B interelement bond related to catalysis
Author(s): Feng, Jian-Jun
Mao, Wenbin
Zhang, Liangliang
Oestreich, Martin
Type: Article
Abstract: Si–B reagents, namely silylboronic esters and silylboranes, have become increasingly attractive as versatile reagents to introduce silicon and boron atoms into organic frameworks. Diverse transformations through transition-metal-catalysed or transition-metal-free Si–B bond activation have become available. This Review summarises the recent developments in the now broad field of Si–B chemistry and covers the literature from the last seven years as an update of our review on the same topic published in early 2013 (M. Oestreich, E. Hartmann and M. Mewald, Chem. Rev., 2013, 113, 402–441). It mainly focuses on new applications of Si–B reagents but new methods of their preparation and, where relevant, reaction mechanisms are also discussed.
Subject(s): catalysis
Si–B reagents
organic frameworks
Issue Date: 16-Dec-2020
Date Available: 11-Mar-2021
Language Code: en
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Sponsor/Funder: TU Berlin, Open-Access-Mittel – 2020
Journal Title: Chemical Society Reviews
Publisher: Royal Society of Chemistry
Volume: 50
Issue: 3
Publisher DOI: 10.1039/D0CS00965B
Page Start: 2010
Page End: 2073
EISSN: 1460-4744
ISSN: 0306-0012
TU Affiliation(s): Fak. 2 Mathematik und Naturwissenschaften » Inst. Chemie » FG Organische Chemie / Synthese und Katalyse
Appears in Collections:Technische Universität Berlin » Publications

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