Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-11921
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Main Title: Dosing Free Nitrous Acid as an Alternative Sulphide Control Technology for Pressure Sewers in Germany
Author(s): Despot, Daneish
Reinhold, Luisa
Augustyniak, Adrian
Barjenbruch, Matthias
Type: Article
URI: https://depositonce.tu-berlin.de/handle/11303/13127
http://dx.doi.org/10.14279/depositonce-11921
License: https://creativecommons.org/licenses/by/4.0/
Abstract: Sulphide build-up in pressure sewers has been identified as the main cause for the occurrence of odour and corrosion in sewer systems. Despite the efforts to optimize commonly used control technologies such as nitrate and iron salts to reduce sulphide emission, continuous addition of these chemicals is still required. A biocidal agent such as free nitrous acid can be added intermittently, less frequently, and in smaller quantities whilst achieving total sulphide control. So far, laboratory and field studies in Australia and the USA have successfully proven and applied the use of this control technology, exhibiting its strong biocidal effects during intermittent addition. In this study, nine trials were made to assess the application of the free nitrous acid (FNA) as an alternative sulphide control technology in Germany. The sewer pilot plant of the Berlin Water Utility Company was used to perform the trials at a technical scale using a supply of raw sewage. FNA exposure times ranging from 5 to 24 h in varying concentrations were investigated. The effectiveness of the FNA treatment was monitored using the online hydrogen sulphide (H2S) gas and dissolved-sulphide sensors installed in the sewer pilot plant. Effective sulphide control was only possible during dosing periods, with rapid resumption of sulphide production for the trials with exposure times of <12 h and concentrations ranging from 0.08 to 0.56 mg HNO2-N L−1 suggesting a slight inhibitory effect. A more pronounced biocidal effect was observed for the trials exposed to FNA treatment for 24 h at concentrations >0.29 mg HNO2-N L−1. Overall, the trials of this study demonstrated that the biofilms were FNA resistant and that the concentrations and exposure times used were inadequate to develop an effective intermittent dosing strategy.
Subject(s): sulphide control
pressure sewers
free nitrous acid
intermittent dosage
Issue Date: 8-Apr-2021
Date Available: 19-May-2021
Language Code: en
DDC Class: 620 Ingenieurwissenschaften und zugeordnete Tätigkeiten
Sponsor/Funder: DFG, 248198858, GRK 2032: Grenzzonen in urbanen Wassersystemen
DFG, 414044773, Open Access Publizieren 2021 - 2022 / Technische Universität Berlin
Journal Title: Water
Publisher: MDPI
Volume: 13
Issue: 8
Article Number: 1015
Publisher DOI: 10.3390/w13081015
EISSN: 2073-4441
TU Affiliation(s): Fak. 6 Planen Bauen Umwelt » Inst. Bauingenieurwesen » FG Siedlungswasserwirtschaft
Appears in Collections:Technische Universität Berlin » Publications

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