Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-12072
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Main Title: At Long Last: The Me3Si Group as a Masked Alcohol
Author(s): Roy, Avijit
Oestreich, Martin
Type: Article
URI: https://depositonce.tu-berlin.de/handle/11303/13280
http://dx.doi.org/10.14279/depositonce-12072
License: https://creativecommons.org/licenses/by/4.0/
Abstract: For a long time, the Me3Si group has been ostracized from the family of aryl‐ and heteroatom‐substituted congeners for the difficulties associated with its further chemoselective manipulation into another synthetically useful functional group. A hypervalent iodine reagent has now been shown to do exactly that by electrophilic demethylation. Coupled with the Tamao–Fleming oxidation, the Me3Si group becomes a placeholder for a hydroxy group.
Subject(s): alcohols
density functional calculations
hypervalent compounds
silicon
Tamao–Fleming oxidation
Issue Date: 26-Jan-2021
Date Available: 24-Jun-2021
Language Code: en
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Sponsor/Funder: TU Berlin, Open-Access-Mittel – 2021
Journal Title: Angewandte Chemie
Publisher: Wiley
Volume: 60
Issue: 9
Publisher DOI: 10.1002/anie.202017157
Page Start: 4408
Page End: 4410
EISSN: 1521-3773
ISSN: 1433-7851
TU Affiliation(s): Fak. 2 Mathematik und Naturwissenschaften » Inst. Chemie » FG Organische Chemie / Synthese und Katalyse
Appears in Collections:Technische Universität Berlin » Publications

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