Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-16075
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Main Title: Synthesis of light hydrocarbons from biogas and hydrogen: Investigation of a Fe-Mn-K/MgO catalyst
Author(s): Dietrich, Sebastian
Nieß, Selina
Rönsch, Stefan
Kraume, Matthias
Type: Article
URI: https://depositonce.tu-berlin.de/handle/11303/17294
http://dx.doi.org/10.14279/depositonce-16075
License: https://creativecommons.org/licenses/by/4.0/
Abstract: Fischer-Tropsch synthesis of the CO2 in biogas aims at producing light hydrocarbons and increasing its calorific value for feeding into the grid. Fe catalysts with Mn and K as promoters are supposed to yield high amounts of light hydrocarbons. Using a Fe-Mn-K/MgO catalyst, a parameter screening and long-term experiments were carried out. The catalyst shows, within the examined range, the highest selectivity to C2–C4 hydrocarbons at 450 °C, 8 bar(a), and a gas hourly space velocity of 350 h−1. Calcination of the catalyst resulted in a significant drop of activity and an almost complete loss of selectivity to hydrocarbons. Admixture of steam to the reactant gas lowers the tendency to carbon deposition but also promotes the water-gas shift reaction and results in lower yields of hydrocarbons.
Subject(s): biogas
catalyst
Fischer-Tropsch synthesis
light hydrocarbons
Power-to-X
Issue Date: 19-May-2020
Date Available: 3-Aug-2022
Language Code: en
DDC Class: 660 Chemische Verfahrenstechnik
Journal Title: Chemical Engineering and Technology
Publisher: Wiley
Volume: 43
Issue: 8
Publisher DOI: 10.1002/ceat.202000035
Page Start: 1547
Page End: 1553
EISSN: 1521-4125
ISSN: 0930-7516
TU Affiliation(s): Fak. 3 Prozesswissenschaften » Inst. Prozess- und Verfahrenstechnik » FG Verfahrenstechnik
Appears in Collections:Technische Universität Berlin » Publications

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