Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-5189
Main Title: Synthesis and vibrational spectroscopy of Fe-57-labeled models of [NiFe] hydrogenase: first direct observation of a nickel-iron interaction
Author(s): Schilter, David
Pelmenschikov, Vladimir
Wang, Hongxin
Meier, Florian
Gee, Leland B.
Yoda, Yoshitaka
Kaupp, Martin
Rauchfuss, Thomas B.
Cramer, Stephen P.
Type: Article
Language Code: en
Abstract: A new route to iron carbonyls has enabled synthesis of 57Fe-​labeled [NiFe] hydrogenase mimic (OC)​357Fe(pdt)​Ni(dppe) (pdt = 1,​3-​propanedithiolate)​. Its study by nuclear resonance vibrational spectroscopy revealed Ni-​57Fe vibrations, as confirmed by calcns. The modes are absent for [(OC)​357Fe(pdt)​Ni(dppe)​]​+, which lacks Ni-​57Fe bonding, underscoring the utility of the analyses in identifying metal-​metal interactions.
URI: http://depositonce.tu-berlin.de/handle/11303/5560
http://dx.doi.org/10.14279/depositonce-5189
Issue Date: 2014
Date Available: 21-Jun-2016
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Creative Commons License: https://creativecommons.org/licenses/by/3.0/
Journal Title: Chemical communications
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 50
Issue: 88
Publisher DOI: 10.1039/c4cc04572f
Page Start: 13469
Page End: 13472
EISSN: 1364-548X
ISSN: 1359-7345
Appears in Collections:Technische Universität Berlin » Fakultäten & Zentralinstitute » Fakultät 2 Mathematik und Naturwissenschaften » Institut für Chemie » Publications

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