Please use this identifier to cite or link to this item:
Main Title: Tuning porosity and activity of microporous polymer network organocatalysts by co-polymerisation
Author(s): Schmidt, Johannes
Kundu, Dipti Sankar
Blechert, Siegfried
Thomas, Arne
Type: Article
Language Code: en
Abstract: Microporous polymer networks based on binaphthyl phosphoric acids are suitable heterogeneous asymmetric organocatalysts. Herein we show that the porous characteristics of such networks can be fine-tuned by co-polymerisation. This enables us to investigate the influence of the surface area and porosity in microporous networks on their catalytic performance. In this case, the activity of the polymers in an asymmetric hydrogenation reaction is increased by the use of polymers with higher surface areas.
Issue Date: 2014
Date Available: 22-Jun-2016
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Sponsor/Funder: EC/FP7/278593/EU/Organic Zeolites/ORGZEO
DFG, EXC 314, Unifying Concepts in Catalysis
Journal Title: Chemical communications
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 50
Issue: 25
Publisher DOI: 10.1039/c3cc49220f
Page Start: 3347
Page End: 3349
EISSN: 1359-7345
Appears in Collections:Inst. Chemie » Publications

Files in This Item:
File Description SizeFormat 
c3cc49220f.pdf1.12 MBAdobe PDFThumbnail

This item is licensed under a Creative Commons License Creative Commons