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Main Title: Comparison of phase transfer agents in the aqueous biphasic hydroformylation of higher alkenes
Author(s): Nowothnick, Henriette
Rost, Anke
Hamerla, Tobias
Schomäcker, Reinhard
Müller, Christian
Vogt, Dieter
Type: Article
Language Code: en
Abstract: The Rh-catalyzed aqueous biphasic hydroformylation with the bidentate ligand SulfoXantPhos was investigated for different phase transfer agents (PTA). As such, polymer latices and microemulsions formed by non-ionic surfactants were used. In general, a higher PTA concentration enhances the reaction progress. The feasibility of catalyst recycling by simple phase separation is shown in principle. The Rh losses are low in the surfactant system and promising for a technical approach.
Issue Date: 2013
Date Available: 22-Jun-2016
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Sponsor/Funder: EC/FP7/215193/EU/Homogeneous supported catalyst technologies: the sustainable approach to highly-selective, fine chemicals production/NANO-HOST
DFG, TRR 63, Integrierte chemische Prozesse in flüssigen Mehrphasensystemen
Journal Title: Catalysis science & technology : a multidisciplinary journal focussing on all fundamental science and technological aspects of catalysis
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 3
Issue: 3
Publisher DOI: 10.1039/c2cy20629c
Page Start: 600
Page End: 605
EISSN: 2044-4753
Notes: Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Appears in Collections:FG Mehrphasenreaktionstechnik » Publications

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