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Main Title: Mechanistic studies of CO2 reduction to methanol mediated by an N-heterocyclic germylene hydride
Author(s): Tan, Gengwen
Wang, Wenyuan
Blom, Burgert
Drieß, Matthias
Type: Article
Language Code: en
Abstract: The labile germylene hydride LCyGeH is capable of activating CO2 affording the corresponding formate LCyGeOCH([double bond, length as m-dash]O) (2) (LCy = cyclo-C6H8-1-NAr-2-C(Ph)NAr, Ar = 2,6-iPr2C6H3). Compound 2 and the previously reported LGeOCH([double bond, length as m-dash]O) (L = CH(MeC[double bond, length as m-dash]NAr)2, Ar = 2,6-iPr2C6H3) (2′) could be further converted to methanol with the AlH3·NMe3 alane-amine adduct as a hydrogen source upon workup with water. A plausible mechanism for the conversion of the formate complexes to methanol is proposed based on additional results from the conversion of 2′ with the milder hydride delivery agent LAlH2.
Issue Date: 2014
Date Available: 23-Jun-2016
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Sponsor/Funder: DFG, EXC 314, Unifying Concepts in Catalysis
Journal Title: Dalton transactions : a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 43
Issue: 16
Publisher DOI: 10.1039/c3dt53321b
Page Start: 6006
Page End: 6011
EISSN: 1477-9226
Notes: Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Appears in Collections:FG Metallorganische Chemie und Anorganische Materialien » Publications

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