Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-5237
Main Title: Mechanistic studies of CO2 reduction to methanol mediated by an N-heterocyclic germylene hydride
Author(s): Tan, Gengwen
Wang, Wenyuan
Blom, Burgert
Drieß, Matthias
Type: Article
Language Code: en
Abstract: The labile germylene hydride LCyGeH is capable of activating CO2 affording the corresponding formate LCyGeOCH([double bond, length as m-dash]O) (2) (LCy = cyclo-C6H8-1-NAr-2-C(Ph)NAr, Ar = 2,6-iPr2C6H3). Compound 2 and the previously reported LGeOCH([double bond, length as m-dash]O) (L = CH(MeC[double bond, length as m-dash]NAr)2, Ar = 2,6-iPr2C6H3) (2′) could be further converted to methanol with the AlH3·NMe3 alane-amine adduct as a hydrogen source upon workup with water. A plausible mechanism for the conversion of the formate complexes to methanol is proposed based on additional results from the conversion of 2′ with the milder hydride delivery agent LAlH2.
URI: http://depositonce.tu-berlin.de/handle/11303/5608
http://dx.doi.org/10.14279/depositonce-5237
Issue Date: 2014
Date Available: 23-Jun-2016
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Sponsor/Funder: DFG, EXC 314, Unifying Concepts in Catalysis
Usage rights: Terms of German Copyright Law
Journal Title: Dalton transactions : a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 43
Issue: 16
Publisher DOI: 10.1039/c3dt53321b
Page Start: 6006
Page End: 6011
EISSN: 1477-9226
Notes: Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Appears in Collections:Technische Universität Berlin » Fakultäten & Zentralinstitute » Fakultät 2 Mathematik und Naturwissenschaften » Institut für Chemie » Fachgebiet Metallorganische Chemie und Anorganische Materialien » Publications

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