Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-5240
Main Title: Synthesis, characterization and reactivity of an imidazolin-2-iminato aluminium dihydride
Author(s): Franz, Daniel
Irran, Elisabeth
Inoue, Shigeyoshi
Type: Article
Language Code: en
Abstract: The reaction of bis(2,6-diisopropylphenyl)imidazolin-2-imine (LH, 1) with Me3N·AlH3furnishes {μ-LAlH2}2(2). The marked tendency of2to release its hydride substituents is ascribed to the strong electron-donor character of the imidazolin-2-iminato ligand. This is supported by its reactivity study and DFT calculations. In fact, compound2was further converted with Me3SiOTf, Me2S·BH3, Me2S·BBr3, and BX3(with X = Cl, Br, and I) into {μ-LAl(H)OTf}2(3), {μ-LAl(BH4)2}2(4), and {μ-LAlX2}2(5, X = Br;6, X = Cl;7, X = I), respectively. For all new aluminium complexes the formulation as dimers was evidenced by high resolution mass spectrometry, as well as single-crystal X-ray diffraction analysis. A prominent structural motif of these compounds is the square-planar four-membered Al2N2ring with two bridging bulky imidazolin-2-imino moieties.
URI: http://depositonce.tu-berlin.de/handle/11303/5611
http://dx.doi.org/10.14279/depositonce-5240
Issue Date: 2014
Date Available: 23-Jun-2016
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Usage rights: Terms of German Copyright Law
Journal Title: Dalton transactions : a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 43
Issue: 11
Publisher DOI: 10.1039/c3dt52637b
Page Start: 4451
Page End: 4461
EISSN: 1477-9226
Notes: Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Appears in Collections:Technische Universität Berlin » Fakultäten & Zentralinstitute » Fakultät 2 Mathematik und Naturwissenschaften » Institut für Chemie » Publications

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