Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-5254
Main Title: Doping carbons beyond nitrogen: an overview of advanced heteroatom doped carbons with boron, sulphur and phosphorus for energy applications
Author(s): Paraknowitsch, Jens Peter
Thomas, Arne
Type: Article
Language Code: en
Abstract: Heteroatom doped carbon materials represent one of the most prominent families of materials that are used in energy related applications, such as fuel cells, batteries, hydrogen storage or supercapacitors. While doping carbons with nitrogen atoms has experienced great progress throughout the past decades and yielded promising material concepts, also other doping candidates have gained the researchers' interest in the last few years. Boron is already relatively widely studied, and as its electronic situation is contrary to the one of nitrogen, codoping carbons with both heteroatoms can probably create synergistic effects. Sulphur and phosphorus have just recently entered the world of carbon synthesis, but already the first studies published prove their potential, especially as electrocatalysts in the cathodic compartment of fuel cells. Due to their size and their electronegativity being lower than those of carbon, structural distortions and changes of the charge densities are induced in the carbon materials. This article is to give a state of the art update on the most recent developments concerning the advanced heteroatom doping of carbon that goes beyond nitrogen. Doped carbon materials and their applications in energy devices are discussed with respect to their boron-, sulphur- and phosphorus-doping.
URI: http://depositonce.tu-berlin.de/handle/11303/5634
http://dx.doi.org/10.14279/depositonce-5254
Issue Date: 2013
Date Available: 24-Jun-2016
DDC Class: 690 Hausbau, Bauhandwerk
Usage rights: Terms of German Copyright Law
Journal Title: Energy & environmental science
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 6
Issue: 10
Publisher DOI: 10.1039/c3ee41444b
Page Start: 2839
Page End: 2855
EISSN: 1754-5692
Notes: Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Appears in Collections:Technische Universität Berlin » Fakultäten & Zentralinstitute » Fakultät 2 Mathematik und Naturwissenschaften » Institut für Chemie » Fachgebiet Funktionsmaterialien » Publications

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