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Main Title: The preparation, characterisation and electronic structures of 2,4-pentadiynylnitrile (cyanobutadiynyl) complexes
Author(s): Bock, Sören
Eaves, Samantha G.
Parthey, Matthias
Kaupp, Martin
Guennic, Boris le
Halet, Jean-François
Yufit, Dmitry S.
Howard, Judith A. K.
Low, Paul J.
Type: Article
Language Code: en
Abstract: Convenient preparative routes to mononuclear ruthenium complexes containing the 2,4-pentadiynylnitrile, or cyanobutadiynyl, ligand are described. The electronic properties of the [C5N]− ligand are closely related to those of not only the cyanide ([CN]−) and 2-propynylnitrile or cyanoacetylide ([C[triple bond, length as m-dash]CC[triple bond, length as m-dash]N]−) ligands, but also those of the isoelectronic polyynyl ([{C[triple bond, length as m-dash]C}nR]−) ligands.
Issue Date: 2013
Date Available: 27-Jun-2016
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Journal Title: Dalton transactions : a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 42
Issue: 12
Publisher DOI: 10.1039/c3dt33052d
Page Start: 4240
Page End: 4243
EISSN: 1477-9226
Notes: Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Appears in Collections:FG Technische Chemie » Publications

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