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Main Title: Catalytic dehydrogenative Si-N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base
Author(s): Königs, C. David F.
Müller, Maria F.
Aiguabella, Nuria
Klare, Hendrik F. T.
Oestreich, Martin
Type: Article
Language Code: en
Abstract: A base-free, catalytic protocol for the dehydrogenative Si–N coupling of weakly nucleophilic N–H groups of heteroarenes or aryl-substituted amines with equimolar amounts of hydrosilanes is reported. Cooperative Si–H bond activation at a Ru–S bond generates a silicon electrophile that forms a Si–N bond prior to the N–H deprotonation by an intermediate Ru–H complex, only releasing H2.
Issue Date: 2013
Date Available: 27-Jun-2016
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Sponsor/Funder: DFG, GRK 1143, Komplexe chemische Systeme: Design, Entwicklung und Anwendungen
Journal Title: Chemical communications
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 49
Issue: 15
Publisher DOI: 10.1039/c3cc38900f
Page Start: 1506
Page End: 1508
EISSN: 1359-7345
Notes: Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Appears in Collections:Inst. Chemie » Publications

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