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Main Title: Taming the germyliumylidene [CIGe:](+) and germathionium [CIGe=S](+) ions by donor-acceptor stabilization using 1,8-bis(tributylphosphazenyl)naphthalene
Author(s): Xiong, Yun
Yao, Shenglai
Inoue, Shigeyoshi
Berkefeld, Andreas
Drieß, Matthias
Type: Article
Language Code: en
Abstract: The novel chlorogermyliumylidene complex L[ClGe:]+ (L = 1,8-bis(tri-n-butylphosphanzenyl)naphthalene) with a ‘naked’ Cl− as a counter anion was synthesized through reaction of L with Cl2Ge: and fully characterized. Its reaction with elemental sulfur afforded the first germathionium [ClGe[double bond, length as m-dash]S]+ cation containing species. The latter has also been fully characterized, including single-crystal X-ray diffraction analysis.
Issue Date: 2012
Date Available: 28-Jun-2016
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Journal Title: Chemical communications
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 48
Issue: 100
Publisher DOI: 10.1039/c2cc36926e
Page Start: 12198
Page End: 12200
EISSN: 1359-7345
Notes: Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Appears in Collections:FG Metallorganische Chemie und Anorganische Materialien » Publications

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