Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-5334
Main Title: Rollover cyclometalation - early history, recent developments, mechanistic insights and application aspects
Author(s): Butschke, Burkhard
Schwarz, Helmut
Type: Article
Language Code: en
Abstract: “Rollover” cyclometalation constitutes a special case among the well-known class of cyclometalation reactions. An overview is given that covers the very first description of this reaction type, as well as recent developments. In addition, not only condensed-phase experiments are reviewed, but also investigations based on mass spectrometric techniques, together with “in silico” studies using DFT-based calculations are considered. While the latter two methods allow for a detailed analysis of the intrinsic factors that affect the reaction mechanisms, consideration of all three regimes permits to develop a coherent mechanistic picture and to address the often noted gap between condensed- and gas-phase studies. Moreover, the quite unexpected reactivity of “rollover” cyclometalated complexes in gas-phase experiments, as well as potential applications, e.g. in synthetic procedures, are discussed in some detail.
URI: http://depositonce.tu-berlin.de/handle/11303/5714
http://dx.doi.org/10.14279/depositonce-5334
Issue Date: 2012
Date Available: 29-Jun-2016
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Sponsor/Funder: DFG, EXC 314, Unifying Concepts in Catalysis
Usage rights: Terms of German Copyright Law
Journal Title: Chemical science
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 3
Issue: 2
Publisher DOI: 10.1039/c1sc00651g
Page Start: 308
Page End: 326
EISSN: 2041-6520
Notes: Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Appears in Collections:Technische Universität Berlin » Fakultäten & Zentralinstitute » Fakultät 2 Mathematik und Naturwissenschaften » Institut für Chemie » Publications

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