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Main Title: A straightforward zinc-catalysed reduction of sulfoxides to sulfides
Author(s): Enthaler, Stephan
Type: Article
Language Code: en
Abstract: In the present study, the zinc-catalysed reduction of a variety of sulfoxides with silanes as reductant to the corresponding sulfide has been examined in detail. With the straightforward and commercially available zinc(II) triflate as pre-catalyst, excellent yields and chemoselectivities were feasible. After studying the reaction conditions and the scope and limitations several attempts were undertaken to shed light on the reaction mechanism.
Issue Date: 2011
Date Available: 30-Jun-2016
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Sponsor/Funder: DFG, EXC 314, Unifying Concepts in Catalysis
Journal Title: Catalysis science & technology : a multidisciplinary journal focussing on all fundamental science and technological aspects of catalysis
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 1
Issue: 1
Publisher DOI: 10.1039/c0cy00039f
Page Start: 104
Page End: 110
EISSN: 2044-4761
ISSN: 2044-4753
Notes: Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Appears in Collections:EXC - UniCat » Publications

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