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Main Title: Formation of N-heterocyclic, donor-stabilized borenium ions
Author(s): Someya, Chika I.
Inoue, Shigeyoshi
Präsang, Carsten
Irran, Elisabeth
Drieß, Matthias
Type: Article
Language Code: en
Abstract: Cationic and zwitterionic boryl bromide species and a borenium–boryl bromide cation have been synthesised which represent new N-donor stabilised cationic boron compounds with β-diketiminate ligands. The unexpected borenium–boryl bromide results from a head-to-tail dimerisation of the corresponding zwitterionic boryl bromide accompanied by proton migration. The electronic nature of these new species was studied by DFT calculations.
Issue Date: 2011
Date Available: 30-Jun-2016
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Usage rights: Terms of German Copyright Law
Journal Title: Chemical communications
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 47
Issue: 23
Publisher DOI: 10.1039/c1cc11789k
Page Start: 6599
Page End: 6601
EISSN: 1364-548X
ISSN: 1359-7345
Notes: Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Appears in Collections:Fachgebiet Metallorganische Chemie und Anorganische Materialien » Publications

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