Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-5361
Main Title: Synthesis of mesoporous composite materials of nitrogen-doped carbon and silica using a reactive surfactant approach
Author(s): Paraknowitsch, Jens Peter
Zhang, Yuanjian
Thomas, Arne
Type: Article
Language Code: en
Abstract: Mesoporous composite materials of nitrogen-doped carbon and silica were synthesised in a one-step-process applying a soft templating procedure. The template used in the sol–gel synthesis of the silica is a cationic surfactant with distinct reactivity to form nitrogen-doped graphitic carbon upon heating. This reactivity is derived from the combination of the dicyanamide anion with a nitrogen-containing pyridinium cation, as it is known from ionic liquids used as nitrogen-doped carbon precursors. Thus applying this surfactant in a conventional sol–gel synthesis yields a silica gel doped with a precursor for N-doped carbon. By subsequent annealing mesoporous composite materials of silica and nitrogen-doped carbon are obtained.
URI: http://depositonce.tu-berlin.de/handle/11303/5741
http://dx.doi.org/10.14279/depositonce-5361
Issue Date: 2011
Date Available: 30-Jun-2016
DDC Class: 540 Chemie und zugeordnete Wissenschaften
530 Physik
Usage rights: Terms of German Copyright Law
Journal Title: Journal of materials chemistry
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 21
Issue: 39
Publisher DOI: 10.1039/c1jm11633a
Page Start: 15537
Page End: 15543
EISSN: 1364-5501
ISSN: 0959-9428
Notes: Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Appears in Collections:Fachgebiet Funktionsmaterialien » Publications

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