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| Main Title: | (OC-6-13)-Difluoridooxidobis(propan-2-ol)(propan-2-olato)vanadium(V) |
| Author(s): | Kohl, Julia Wiedemann, Dennis |
| Type: | Article |
| Language Code: | en |
| Abstract: | The distorted octahedral title complex, [V-V(C3H7O)(C3H8O)(2)F2O], was synthesized via ligand exchange at [(VO)-O-V(OiPr)(3)] with aqueous hydrogen fluoride in propan-2-ol and crystallized from (D) chloroform at 238 K after a few weeks. Crystal structure determination shows two C-1-symmetric moieties to be present in the asymmetric unit, forming infinite chains along [100] via hydrogen bonds. The compound provides the first crystal structure containing the [VF2O(OiPr)] motif. |
| URI: | http://depositonce.tu-berlin.de/handle/11303/5894 http://dx.doi.org/10.14279/depositonce-5487 |
| Issue Date: | 2013 |
| Date Available: | 13-Sep-2016 |
| DDC Class: | 540 Chemie und zugeordnete Wissenschaften 530 Physik |
| Subject(s): | crystal structure vanadium complexes alcoholates hydrogen fluoride hydrogen bonds |
| License: | http://rightsstatements.org/vocab/InC/1.0/ |
| Journal Title: | Acta Crystallographica Section C : Structural Chemistry |
| Publisher: | Wiley-Blackwell |
| Publisher Place: | Oxford |
| Volume: | 69 |
| Issue: | 12 |
| Publisher DOI: | 10.1107/S0108270113029776 |
| Page Start: | 1482 |
| Page End: | 1484 |
| EISSN: | 1600-5759 |
| ISSN: | 0108-2701 |
| Appears in Collections: | FG Anorganische Chemie - Festkörper- und Materialchemie » Publications |
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