Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-6011
Main Title: Transfer hydrosilylation
Author(s): Oestreich, Martin
Type: Article
Language Code: en
Abstract: Transfer hydrogenation is without question a common technology in industry and academia. Unlike its countless varieties, conceptually related transfer hydrosilylations had essentially been unreported until the recent development of a radical and an ionic variant. The new methods are both based on a silicon-substituted cyclohexa-1,4-diene and hinge on the aromatization of the corresponding cyclohexadienyl radical and cation intermediates, respectively, concomitant with homo-or heterolytic fission of the Si-C bond. Both the radical and ionic transfer hydrosilylation are brought into context with one other in this Minireview, and early insight into the possibility of transfer hydrosilylation is included. Although the current state-of-the-art is certainly still limited, the recent advances have already revealed the promising potential of transfer hydrosilylation.
URI: http://depositonce.tu-berlin.de/handle/11303/6503
http://dx.doi.org/10.14279/depositonce-6011
Issue Date: 2016
Date Available: 14-Jul-2017
DDC Class: DDC::500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
Subject(s): cations
cyclohexa-1,4-dienes
hydrosilylation
radicals
silane transfer
Creative Commons License: https://creativecommons.org/licenses/by-nc-nd/4.0/
Journal Title: Angewandte Chemie - International Edition
Publisher: Wiley-VCH
Publisher Place: Weinheim
Volume: 55
Issue: 2
Publisher DOI: 10.1002/anie.201508879
Page Start: 494
Page End: 499
EISSN: 1521-3773
ISSN: 1433-7851
References: http://dx.doi.org/10.14279/depositonce-6012
Appears in Collections:Technische Universität Berlin » Fakultäten & Zentralinstitute » Fakultät 2 Mathematik und Naturwissenschaften » Institut für Chemie » Fachgebiet Organische Chemie / Synthese und Katalyse » Publications

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