Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-6246
Main Title: Phosphinosilylenes as a novel ligand system for heterobimetallic complexes
Author(s): Breit, Nora C.
Eisenhut, Carsten
Inoue, Shigeyoshi
Type: Article
Language Code: en
Abstract: A dihydrophosphinosilylene iron complex [LSi{Fe(CO)(4)}PH2] has been prepared and utilized in the synthesis of novel heterobimetallic complexes. The phosphine moiety in this phosphinosilylene complex allows coordination towards tungsten leading to the iron-tungsten heterobimetallic complex [LSi{Fe(CO)(4)}PH2{W(CO)(5)}]. In contrast, the reaction of [LSi{Fe(CO)(4)}PH2] with ethylenebis(triphenylphosphine)platinum(0) results in the formation of the iron-platinum heterobimetallic complex [LSi{Fe(CO)(4)}PH{PtH(PPh3)(2)}] via oxidative addition.
URI: https://depositonce.tu-berlin.de//handle/11303/6907
http://dx.doi.org/10.14279/depositonce-6246
Issue Date: 2016
Date Available: 24-Oct-2017
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Creative Commons License: https://creativecommons.org/licenses/by/3.0/
Journal Title: Chemical communications
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 52
Issue: 32
Publisher DOI: 10.1039/c6cc00601a
Page Start: 5523
Page End: 5526
EISSN: 1364-548X
ISSN: 1359-7345
Appears in Collections:Fachgebiet Anorganische Chemie - Festkörper- und Materialchemie » Publications

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