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Main Title: Isolation of a germanium(II) cation and a germylene iron carbonyl complex utilizing an imidazolin-2-iminato ligand
Author(s): Ochiai, Tatsumi
Franz, Daniel
Wu, Xiao-Nan
Inoue, Shigeyoshi
Type: Article
Language Code: en
Abstract: The novel amino(imino)germylene 1 was prepared by the conversion of HNIPr (NIPr = bis(2,6-diisopropylphenyl) imidazolin-2-imino) with 1 equiv. of Ge[N(SiMe3)(2)](2). Germylene 1 reacts with B (C6F5)(3) to afford the borate salt 2(+)[MeB(C6F5)(3)](-) in a methyl-abstraction and ring-closing reaction. The conversion of 2 with Fe-2(CO)(9) furnishes the germylene iron carbonyl complex 3 with a trigonal planar-coordinate germanium atom.
Issue Date: 2015
Date Available: 25-Oct-2017
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Journal Title: Dalton transactions
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 44
Issue: 24
Publisher DOI: 10.1039/c5dt01554e
Page Start: 10952
Page End: 10956
EISSN: 1477-9234
ISSN: 1477-9226
Notes: Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
Appears in Collections:FG Anorganische Chemie - Festkörper- und Materialchemie » Publications

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