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Main Title: Reductive cleavage of P-4 by iron(I) centres: synthesis and structural characterisation of Fe-2(P-2)(2) complexes with two bridging P-2(2-) ligands
Author(s): Yao, Shenglai
Szilvási, Tibor
Lindenmaier, Nils
Xiong, Yun
Inoue, Shigeyoshi
Adelhardt, Mario
Sutter, Jörg
Meyer, Karsten
Drieß, Matthias
Type: Article
Language Code: en
Abstract: The selective transformation of white phosphorus with a beta-diketiminato iron(I) toluene complex under mild reaction conditions is reported which furnishes a new dinuclear iron(III) Fe-2(P-2)(2) complex with two bridging P-2(2-) ligands. Its reduction with potassium results in the formation of the first delocalised mixed-valent bis-diphosphido iron(II,III) complex which is isostructural with the neutral Fe2P4 precursor.
Issue Date: 2015
Date Available: 25-Oct-2017
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Journal Title: Chemical communications
Publisher: Royal Society of Chemistry
Publisher Place: Cambridge
Volume: 51
Issue: 28
Publisher DOI: 10.1039/c5cc00147a
Page Start: 6153
Page End: 6156
EISSN: 1364-548X
ISSN: 1359-7345
Appears in Collections:FG Metallorganische Chemie und Anorganische Materialien » Publications

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