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Main Title: Synthesis of a cyclopentadienyl(imino)stannylene and its direct conversion into halo(imino)stannylenes
Author(s): Ochiai, Tatsumi
Inoue, Shigeyoshi
Type: Article
Language Code: en
Abstract: The reaction of stannocene Cp2Sn with iminolithium LiNIPr (NIPr = bis(2,6-diisopropylphenyl)imidazolin-2-iminato) afforded the dimeric cyclopentadienyl(imino)stannylene [(η1-Cp)SnNIPr]2 (1). Compound 1 exhibits unexpected reactivity towards haloalkanes. The high-yield conversion of 1 into chlorostannylene [ClSnNIPr]2 (2) and bromostannylene [BrSnNIPr]2 (3) were accomplished by treatment with dichloromethane or 1,2-dibromoethane, respectively, through a Cp-substitution reaction.
Issue Date: 2017
Date Available: 19-Apr-2018
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Journal Title: RSC Advances
Publisher: Royal Society of Chemistry (RSC)
Publisher Place: London
Volume: 7
Issue: 2
Publisher DOI: 10.1039/c6ra27697k
Page Start: 801
Page End: 804
EISSN: 2046-2069
ISSN: 2046-2069
Appears in Collections:FG Metallorganische Chemie und Anorganische Materialien » Publications

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