Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-7006
Main Title: Higher alcohol synthesis over Rh catalysts: conditioning of Rh/N-CNTs by Co and Mn entrapped in the support
Author(s): Xie, Zailai
Frank, Benjamin
Huang, Xing
Schlögl, Robert
Trunschke, Annette
Type: Article
Language Code: en
Abstract: Rh nanoparticles supported on commercial non-purified N-doped CNTs (NCNTs) containing residual CNT growth catalyst have been studied in hydrogenation of CO to higher alcohols. It has been found that Co and Mn residues in NCNTs are not inert, but change the catalyst under reaction conditions and efficiently promote the catalyst resulting in both increasing activity and selectivity to C2+ alcohols with time on stream.
URI: https://depositonce.tu-berlin.de//handle/11303/7846
http://dx.doi.org/10.14279/depositonce-7006
Issue Date: 13-Oct-2016
Date Available: 25-May-2018
DDC Class: 540 Chemie
660 Chemische Verfahrenstechnik
Subject(s): Rhodium
Cobalt
Manganese
CNT growth catalyst
higher alcohol synthesis
carbon nanotubes
nitrogen doping
nanoparticles
Sponsor/Funder: BMBF, 03X0204C, CarboKat - Einsatz von Carbon Nanotubes als Katalysator und Katalysatorträger
License: https://creativecommons.org/licenses/by/4.0/
Journal Title: Catalysis Letters
Publisher: Springer Science+Business Media
Publisher Place: Dordrecht
Volume: 146
Issue: 12
Publisher DOI: 10.1007/s10562-016-1875-6
Page Start: 2417
Page End: 2424
EISSN: 1572-879X
ISSN: 1011-372X
Appears in Collections:FG Metallorganische Chemie und Anorganische Materialien » Publications

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