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Main Title: Synthesis and Crystal Structure of the New Telluric Acid Adduct (RbCl)3·Te(OH)6
Author(s): Mahlmeister, Dirk
Irran, Elisabeth
Type: Article
Language Code: en
Abstract: The new telluric acid adduct (RbCl)3 ・ Te(OH)6 was prepared by dissolving RbCl and Te(OH)6 in the molar ratio of 3 : 1 in deionized water at r. t. and slow evaporation of the solvent in air. The crystal structure of the colorless crystals was determined with single-crystal X-ray diffraction (trigonal space group: R3̄c (no. 167), a = 14.4392(8), c = 10.4301(16) Å , Z = 6). In (RbCl)3 ・ Te(OH)6, the rubidium atom is surrounded by five chlorine and four oxygen atoms in form of an irregular tricapped trigonal prism. Each tellurium atom is octahedrally surrounded by six oxygen atoms. The Te(OH)6 octahedra and the RbCl5O4 polyhedra are linked to a dense three-dimensional network which is additionally strengthened by hydrogen bonds.
Issue Date: 2012
Date Available: 1-Oct-2018
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): rubidium chloride
telluric acid
crystal structure
Journal Title: Zeitschrift für Naturforschung B
Publisher: De Gruyter
Publisher Place: Berlin
Volume: 67
Issue: 1
Publisher DOI: 10.1515/znb-2012-0101
Page Start: 1
Page End: 4
EISSN: 1865-7117
ISSN: 0932-0776
Appears in Collections:Inst. Chemie » Publications

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