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Main Title: Synthesis, Crystal Structure and Magnetic Properties of Bixbyite-type Vanadium Oxide Nitrides
Author(s): Nakhal, Suliman
Hermes, Wilfried
Ressler, Thorsten
Pöttgen, Rainer
Lerch, Martin
Type: Article
Language Code: en
Abstract: Ammonolysis of vanadium sulfide leads to the formation of bixbyite-type vanadium oxide nitrides. Small amounts of nitrogen incorporated in the structure result in the stabilization of the bixbyite type not known for vanadium oxides. The crystal structure was investigated using X-ray diffraction and X-ray absorption spectroscopy. At temperatures above 550 °C the powders decompose to corundumtype V2O3 containing no detectable amount of nitrogen. Below 39 K magnetic ordering is observed.
Issue Date: 2009
Date Available: 1-Oct-2018
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): oxide nitrides
crystal chemistry
Journal Title: Zeitschrift für Naturforschung B
Publisher: De Gruyter
Publisher Place: Berlin
Volume: 64
Issue: 3
Publisher DOI: 10.1515/znb-2009-0305
Page Start: 281
Page End: 286
EISSN: 1865-7117
ISSN: 0932-0776
Appears in Collections:Inst. Chemie » Publications

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