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Main Title: Deca(4-methylbenzyl)ferrocen und -stannocen
Translated Title: Deca(4-methylbenzyl)ferrocene and -stannocene
Author(s): Schumann, Herbert
Sühring, Klaudia
Weimann, Roman
Hummert, Markus
Type: Article
Language Code: de
Abstract: Cyclopentadiene reacts with five equivalents of 4-methylbenzylalcohol (1:5,6 mole ratio) and sodium yielding penta(4-methylbenzyl)cyclopenta-2,4-diene (1), which upon treatment with butyl lithium affords the lithium salt [(4-MeC6H4CH2)5C5]Li (2). The reactions of 2 with FeCl2 and SnCl2 result in the formation of deca(4-methylbenzyl)ferrocene (3) and deca(4-methylbenzyl)stannocene (4), respectively. The 1H and 13C NMR, IR and mass spectra of the new compounds as well as the single crystal X-ray structure analysis of 1 are reported and discussed.
Issue Date: 2005
Date Available: 15-Oct-2018
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): Cyclopentadiene
Journal Title: Zeitschrift für Naturforschung B
Publisher: De Gruyter
Publisher Place: Berlin
Volume: 60
Issue: 5
Publisher DOI: 10.1515/znb-2005-0508
Page Start: 527
Page End: 532
EISSN: 1865-7117
ISSN: 0932-0776
Appears in Collections:Inst. Chemie » Publications

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