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Main Title: Kristallstruktur des cyanoverbrückten polymeren Zinkcyanid-Pyridin-Komplexes [Zn(py)2][Zn(CN)4]
Translated Title: Crystal Structure of the Cyano Linked Polymeric Zinc Cyanide Pyridine Complex [Zn(py)2][Zn(CN)4]
Author(s): Pickardt, Joachim
Staub, Benedikt
Type: Article
Language Code: de
Abstract: The reaction of aqueous solutions of potassium tetracyanozincate, zinc chloride, and pyridine yields crystals of [Zn(py)2][Zn(CN)4], The crystals are orthorhombic, space group Cccm, a = 926.7(4), b = 1340.8(4), c = 1343.3(4) pm. The structure is polymeric and consists of alternate arrays of tetrahedrally and octahedrally coordinated zinc atoms, bridged by CN ligands. Two pyridine molecules ligate at the axial positions of the octahedrally coordinated zinc atoms.
Issue Date: 1995
Date Available: 10-Nov-2018
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): zinc cyanide pyridine complex
crystal structure
Journal Title: Zeitschrift für Naturforschung B
Publisher: De Gruyter
Publisher Place: Berlin
Volume: 50
Issue: 10
Publisher DOI: 10.1515/znb-1995-1014
Page Start: 1517
Page End: 1520
EISSN: 1865-7117
ISSN: 0932-0776
Appears in Collections:Inst. Chemie » Publications

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