Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-7635
Main Title: Kristallstruktur zweier Zinkthiocyanat-Hexamethylentetramin-Addukte, Zn(SCN)2 · (C6H12N4)2 und {Zn(SCN)2 · C6H12N4 · 2H2O}n, mit unterschiedlich koordinierten Zinkionen
Translated Title: Crystal Structure of Two Zinc Thiocyanate Hexamethylenetetramine Adducts, Zn(SCN)2 · (C6H12N4)2 and {Zn(SCN)2 · C6H12N4 · 2H2O}n with Differently Coordinated Zinc Ions
Author(s): Pickardt, Joachim
Gong, Gill-Taik
Wischnack, Sabine
Steinkopff, Christina
Type: Article
Language Code: de
Abstract: Crystals of the adducts Zn(SCN)2 · (C6H12N4)2 (1), and {Zn(SCN)2 · C6H12N4 · 2H2O}n (2) were obtained by crystallization from aqueous solutions containing hexamethylenetetrami­ne, potassium thiocyanate and zinc nitrate or zinc sulfate, resp., under identical conditions, as two totally different products. 1 crystallizes orthorhombically, space group P nmm, Z = 2, a = 622.4(5), b = 1152.3(7), c = 1394.0(9) pm; 2 is monoclinic, space group C2/c, a = 984.4(3), b = 1217.0(5), c = 1257.4(6) pm, and β = 111.69(5)°. The crystal structure of 1 contains discrete molecules of the complex, in which the zinc ion is tetrahedrally coordinated by two NCS ligands, and two hexamethylenetetramine molecules, which act as monodentate ligands. In 2 however, the zinc ions are octahedrally coordinated. A “supramolecular” structure is form­ed: The hexamethylenetetramine molecules act as bridging bidentate ligands and connect [Zn(H2O)2(NCS)2] units forming zig-zag chains. Adjacent chains are interconnected via hydrogen bonds. The formation of the two compounds with different coordination may be due to the fact, that the educts Zn(NO3)2 · 4H2O and ZnSO4 · 7H2O contain Zn(H2O)4 and Zn(H2O)6 moieties, resp., and that these species are retained in solution.
URI: https://depositonce.tu-berlin.de//handle/11303/8489
http://dx.doi.org/10.14279/depositonce-7635
Issue Date: 1994
Date Available: 10-Nov-2018
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): hexamethylenetetramine complexes
zinc thiocyanate adducts
crystal structure
License: https://creativecommons.org/licenses/by-nc-nd/3.0/
Journal Title: Zeitschrift für Naturforschung B
Publisher: De Gruyter
Publisher Place: Berlin
Volume: 49
Issue: 3
Publisher DOI: 10.1515/znb-1994-0306
Page Start: 325
Page End: 329
EISSN: 1865-7117
ISSN: 0932-0776
Appears in Collections:Inst. Chemie » Publications

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