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Main Title: Metallkomplexe mit 1,4,7-Trithiacyclononan: Kristallstrukturen von [CdI2 · C6H12S3]2 und [Hg(C6H12S3)2](HgI3)2
Translated Title: Metal Complexes with 1,4,7-Trithiacyclononane: Crystal Structures of [CdI2 · C6H12S3]2 and [Hg(C6H12S3)2](HgI3)2
Author(s): Pickardt, Joachim
Shen, Jing
Type: Article
Language Code: de
Abstract: Crystals of the complexes [CdI2 · C6H12S3]2 (1) and [Hg(C6H12S3)2](HgI3)2 (2) were obtained by diffusion of 1,4,7-trithiacyclononane (9 S 3) in ethanol into aqueous solutions of cadmium iodide and mercuric iodide/potassium iodide, resp. Both compounds crystallize monoclinically,1: space group P21/n, Z = 4, a = 1207.1(5), b = 909.9(2), c = 1240.3(7) pm, β = 92.59(9)°; 2: P21/c, Z = 2, a = 804.7(6), b = 934.0(6), c = 2167.9(4) pm, β = 94.34(7)°. 1 is dimeric, consisting of two [CdI2 · 9S3] units, connected via iodine bridges. Crystals of 2 contain sandwich-like cations [Hg(9S3)2]2+ and [HgI3]- anions, forming chains via Hg ··· S and Hg ··· I bridges.
Issue Date: 1993
Date Available: 10-Nov-2018
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): macrocyclic thioethers
cadmium iodide complex
mercuric iodide complex
Journal Title: Zeitschrift für Naturforschung B
Publisher: De Gruyter
Publisher Place: Berlin
Volume: 48
Issue: 7
Publisher DOI: 10.1515/znb-1993-0720
Page Start: 969
Page End: 972
EISSN: 1865-7117
ISSN: 0932-0776
Appears in Collections:Inst. Chemie » Publications

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