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Main Title: Die Kristallstruktur von Hexa-μ-chloro-μ4- oxo - tetrakis [hexamethy lentetramin - kupfer(II)] , [CU4Cl60(C6H12N4)4] , einem Kupfer(II)-Komplex mit Berylliumoxoacetat-ähnlicher Struktur
Translated Title: The Crystal Structure of Hexa-μ-chloro-μ4- oxo-tetrakis [hexamethylenetetraminecopper- (II)], [Cu4Cl6O(C6H12N4)4], a Copper(II) Complex with a Structure Related to that of Beryllium Oxoacetate
Author(s): Pickardt, Joachim
Rautenberg, Norbert
Type: Article
Language Code: de
Abstract: By reaction of solutions of CuCl2·2H2O and hexamethylenetetramine, C6H12N4, in acetone, a complex [Cu4Cl6O(C6H12N4)] could be obtained as single crystals. An X-ray analysis shows that the complex has a structure related to that of basic beryllium acetate. An oxygen atom is tetrahedrally surrounded by four cop-per atoms which, together with six chlorine atoms, form an adamantane-like core. Each copper atom is bonded via a nitrogen atom to a hexamethylenetetramine molecule.
Issue Date: 1982
Date Available: 2-Jan-2019
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): copper(II)complexes
chloro complexes
Journal Title: Zeitschrift für Naturforschung B
Publisher: De Gruyter
Publisher Place: Berlin
Volume: 37
Issue: 10
Publisher DOI: 10.1515/znb-1982-1027
Page Start: 1355
Page End: 1357
EISSN: 1865-7117
ISSN: 0932-0776
Appears in Collections:FG Anorganische Chemie - Festkörper- und Materialchemie » Publications

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