Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-7916
Main Title: Equilibria between Sulfur Rings in Carbon Disulfide Solution at Elevated Temperatures
Author(s): Steudel, Ralf
Strauss, Reinhard
Type: Article
Language Code: en
Abstract: Cyclooctasulfur, S8, dissolved in CS2 reacts at 130-155 °C in sealed ampoules to give S6 and S7 whose concentrations have been determined by HPLC. The half-time of the reaction is independent of the initial S8 concentration and decreases from 232 min at 130 °C to 64 min at 150 °C. After long reaction times equilibrium concentrations are observed which are in agreement with the law of mass action. From the temperature dependence of the equilibrium constants the following reaction enthalpies (at 130-155 °C) have been calculated: 3/4S8⇌S6 ⊿H°=24kJ/mol 7/8S8⇌S7 ⊿H°=21kJ/mol.
URI: https://depositonce.tu-berlin.de//handle/11303/8787
http://dx.doi.org/10.14279/depositonce-7916
Issue Date: 1982
Date Available: 2-Jan-2019
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): elemental sulfur
equilibrium in solution
hplc
thermodynamics
License: https://creativecommons.org/licenses/by-nc-nd/3.0/
Journal Title: Zeitschrift für Naturforschung B
Publisher: De Gruyter
Publisher Place: Berlin
Volume: 37
Issue: 9
Publisher DOI: 10.1515/znb-1982-0924
Page Start: 1219
Page End: 1220
EISSN: 1865-7117
ISSN: 0932-0776
Appears in Collections:FG Anorganische Chemie - Festkörper- und Materialchemie » Publications

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