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Main Title: Vibrational Spectra and Force Constants of Tetrasulfurtetranitride, S4N4 [1]
Author(s): Steudel, Ralf
Type: Article
Language Code: en
Abstract: Infrared and Raman spectra of solid and dissolved S414N4 and of solid S415N4 have been recorded and assigned in accordance with the molecular point group D2d. 22 of the 28 fundamental vibrations of both molecules have been identified and used to calculate force constants applying a modified Urey-Bradley force field with 9 independent constants. Good agreement between observed and calculated wavenumbers was obtained, and both Urey-Bradley and valence force constants are given. The results indicate that-S4N4 basically contains eight SN single bonds and two extremely weak SS bonds.
Issue Date: 1981
Date Available: 4-Jan-2019
DDC Class: 500 Naturwissenschaften und Mathematik
Subject(s): tetrasulfurtetranitride
force constants
vibrational spectra
Journal Title: Zeitschrift für Naturforschung A
Publisher: De Gruyter
Publisher Place: Berlin
Volume: 36
Issue: 8
Publisher DOI: 10.1515/zna-1981-0812
Page Start: 850
Page End: 858
EISSN: 1865-7109
ISSN: 0932-0784
Appears in Collections:FG Anorganische Chemie - Festkörper- und Materialchemie » Publications

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