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Main Title: Metallkomplexe mit Hexamethylentetramin als Ligand: Kristallstruktur des Cadmiumiodid-Addukts 3Cdl2 • 2 C6H12N4 • 4 H2O
Translated Title: Metal Complexes with Hexamethylenetetramine as Ligand: Crystal Structure of the Cadmium Iodide Adduct 3CdI2 • 2C6H12N4 • 4 H2O
Author(s): Pickardt, Joachim
Type: Article
Language Code: de
Abstract: The reaction of aqueous solutions of cadmium iodide and hexamethylenetetramine yields crystals of an adduct 3CdI2 • 2CeH12N4 • 4H2O. The crystals are monoclinic, space group P 21/n, Z = 2, a = 811.5(2), b = 1049.2(4), c = 1849.5(6) pm, β = 97.73(2)°. The adduct is polymeric and may be regarded as built up from groups of two tetrahedrally and one octahedrally coordinated Cd(II) ions in which the tetrahedra and the octahedron are sharing common iodine atoms at the corners; neighbourirg Cd3 units are interlinked by hexamethylenetetramine molecules.
Issue Date: 1981
Date Available: 4-Jan-2019
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): hexamethylenetetramine complexes
cadmium iodide adduct
crystal structure
Journal Title: Zeitschrift für Naturforschung B
Publisher: De Gruyter
Publisher Place: Berlin
Volume: 36
Issue: 10
Publisher DOI: 10.1515/znb-1981-1006
Page Start: 1225
Page End: 1227
EISSN: 1865-7117
ISSN: 0932-0776
Appears in Collections:FG Anorganische Chemie - Festkörper- und Materialchemie » Publications

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