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Main Title: Frontorbitale und 1.2-Hydridwanderungen in Carbeniumionen
Translated Title: Frontier Orbitals and 1,2-Hydrogen Shifts in Carbenium Ions
Author(s): Frenking, Gernot
Schwarz, Helmut
Type: Article
Language Code: de
Abstract: For various carbenium ions it is shown that the energy value and the degree of localization of the LUMO have a significant influence on the energy barriers of 1,2-hydrogen shifts. The structures of the transition states are in line with the Hammond-Postulate.
Issue Date: 1981
Date Available: 4-Jan-2019
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): carbocation chemistry
1,2-hydrogen migration
frontier orbitals
quantum mechanical calculations
transition states
Journal Title: Zeitschrift für Naturforschung B
Publisher: De Gruyter
Publisher Place: Berlin
Volume: 36
Issue: 7
Publisher DOI: 10.1515/znb-1981-0705
Page Start: 797
Page End: 801
EISSN: 1865-7117
ISSN: 0932-0776
Appears in Collections:FG Organische Chemie » Publications

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