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Main Title: Di-μ-iodo-bis [dicarbonyl(di-tert-butylphosphin)ruthenium(I)] (Ru-Ru) und Bis(tri-tert-butylphosphonium)-di-μ-iodo-bis[carbonyl-diiodo- (di-tert-butylphosphin)ruthenium(II)]
Author(s): Schumann, Herbert
Opitz, Joachim
Type: Article
Language Code: de
Abstract: [(t-C4H9)3PH]2[{Ru(μI)I2(CO)[P(t-C4H9)2H]}2] is prepared by the reaction of RUC13 · (H2O)x with CO, NaI, and P(t-C4H9)3 in 2-methoxyethanol. Its IR, Raman, and NMR spectra are reported and discussed. [Ru(μ-I)(CO)2P(t-C4H9)2H)2 is obtained by the reaction of [Ru(μ-I)I(CO)3]2 with P(t-C4H9)3 in 2-methoxyethanol. The X18MAA′M′X′18 spin system of its 1H NMR spectrum is analysed.
Issue Date: 1980
Date Available: 4-Jan-2019
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): ruthenium(i) complex
nmr spectra;
ruthenium(ii) complex
tri-tert-butylphosphonium salt
Journal Title: Zeitschrift für Naturforschung B
Publisher: De Gruyter
Publisher Place: Berlin
Volume: 35
Issue: 1
Publisher DOI: 10.1515/znb-1980-0111
Page Start: 38
Page End: 44
EISSN: 1865-7117
ISSN: 0932-0776
Appears in Collections:FG Anorganische Chemie - Festkörper- und Materialchemie » Publications

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