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Main Title: Röntgenstrukturanalyse und Schwingungsspektren von Trischwefeldistickstoffdioxid, S3N2O2 [1]
Translated Title: X-ray Structural Analysis and Vibrational Spectra of Trisulfurdinitrogendioxide, S3N2O2 [1]
Author(s): Steudel, Ralf
Steidel, Jürgen
Rautenberg, Norbert
Type: Article
Language Code: de
Abstract: A redetermination of the crystal and molecular structure of the chain-like molecule S(NSO)2 resulted in the following molecular parameters: d(SO) = 146.5(2), d(S = N) = 153.4(2), d(S-N) = 165.7(2) pm, bond angles OSN = 117.5(1)°, SNS = 123.6(2)°, and NSN = 97.2(1)°, torsion angles OSNS = -0.3(2)°, and SNSN = -177.7(2)° (molecular symmetry C2). Infrared and Raman spectra of S(NSO)2 are reported and assigned; there is no evidence for conformational changes on dissolution of crystalline S(NSO)2.
Issue Date: 1980
Date Available: 4-Jan-2019
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): sulfur nitrogen compounds
structure|vibrational spectra
Journal Title: Zeitschrift für Naturforschung B
Publisher: De Gruyter
Publisher Place: Berlin
Volume: 35
Issue: 7
Publisher DOI: 10.1515/znb-1980-0702
Page Start: 792
Page End: 796
EISSN: 1865-7117
ISSN: 0932-0776
Appears in Collections:FG Anorganische Chemie - Festkörper- und Materialchemie » Publications

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