Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-8302
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dc.contributor.authorTrunk, Matthias Georg-
dc.contributor.authorHerrmann, Anna-
dc.contributor.authorBildirir, Hakan-
dc.contributor.authorYassin, Ali-
dc.contributor.authorSchmidt, Johannes-
dc.contributor.authorThomas, Arne-
dc.date.accessioned2019-03-14T13:19:03Z-
dc.date.available2019-03-14T13:19:03Z-
dc.date.issued2016-
dc.identifier.issn0947-6539-
dc.identifier.urihttps://depositonce.tu-berlin.de/handle/11303/9219-
dc.identifier.urihttp://dx.doi.org/10.14279/depositonce-8302-
dc.description.abstractA modified one‐pot Sonogashira cross‐coupling reaction based on a copper‐free methodology has been applied for the synthesis of conjugated microporous poly(aryleneethynylene) networks (CMPs) from readily available iodoarylenes and 1,3,5‐triethynylbenzene. The polymerization reactions were carried out by using equimolar amounts of halogen and terminal alkyne moieties with extremely small loadings of palladium catalyst as low as 0.65 mol %. For the first time, CMPs with rigorously controlled structures were obtained without any indications of side reactions, as proven by FTIR and solid‐state NMR spectroscopy, while showing Brunauer–Emmett–Teller (BET) surface areas higher than any poly(aryleneethynylene) network reported before, reaching up to 2552 m2 g−1.en
dc.description.sponsorshipEC/FP7/278593/EU/Organic Zeolites/ORGZEOen
dc.description.sponsorshipDFG, 53182490, EXC 314: Unifying Concepts in Catalysisen
dc.language.isoenen
dc.relation.ispartof10.14279/depositonce-7165-
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/en
dc.subject.ddc540 Chemie und zugeordnete Wissenschaftende
dc.subject.otherCO2 sorptionen
dc.subject.otherconjugated microporous polymersen
dc.subject.othercopper-free Sonogashiraen
dc.subject.othercovalent organic frameworksen
dc.subject.otherhydrogen storageen
dc.titleCopper‐Free Sonogashira Coupling for High‐Surface‐Area Conjugated Microporous Poly(aryleneethynylene) Networksen
dc.typeArticleen
tub.accessrights.dnbdomainen
tub.publisher.universityorinstitutionTechnische Universität Berlinen
dc.identifier.eissn1521-3765-
dc.type.versionacceptedVersionen
dcterms.bibliographicCitation.doi10.1002/chem.201600783en
dcterms.bibliographicCitation.journaltitleChemistry - a European journalen
dcterms.bibliographicCitation.originalpublisherplaceWeinheimen
dcterms.bibliographicCitation.volume22en
dcterms.bibliographicCitation.pageend7183en
dcterms.bibliographicCitation.pagestart7179en
dcterms.bibliographicCitation.originalpublishernameWiley-VCHen
dcterms.bibliographicCitation.issue21en
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