Please use this identifier to cite or link to this item: http://dx.doi.org/10.14279/depositonce-8330
Main Title: Room-Temperature Activation of Hydrogen by Semi-immobilized Frustrated Lewis Pairs in Microporous Polymer Networks
Author(s): Trunk, Matthias Georg
Teichert, Johannes F.
Thomas, Arne
Type: Article
Language Code: en
Is Part Of: 10.14279/depositonce-7165
Abstract: Porous polymer networks based on sterically encumbered triphenylphosphine motifs, mimicking the basic sites employed in frustrated Lewis pair (FLP) chemistry, were synthesized via Yamamoto polymerization and their interactions with the strong Lewis acid B(C6F5)3 probed. The combinations yield semi-immobilized FLPs, which are able to cleave dihydrogen heterolytically at ambient temperature and low hydrogen pressure.
URI: https://depositonce.tu-berlin.de/handle/11303/9253
http://dx.doi.org/10.14279/depositonce-8330
Issue Date: 2017
Date Available: 2-Apr-2019
DDC Class: 540 Chemie und zugeordnete Wissenschaften
Subject(s): frustrated Lewis pairs
microporous polymer networks
room-temperature
activation
hydrogen
Sponsor/Funder: DFG, 53182490, EXC 314: Unifying Concepts in Catalysis
EC/FP7/278593/EU/Organic Zeolites/ORGZEO
License: http://rightsstatements.org/vocab/InC/1.0/
Journal Title: Journal of the American Chemical Society
Publisher: American Chemical Society
Publisher Place: Washington, DC
Volume: 139
Issue: 10
Publisher DOI: 10.1021/jacs.6b13147
Page Start: 3615
Page End: 3618
EISSN: 1520-5126
ISSN: 0002-7863
Appears in Collections:FG Funktionsmaterialien » Publications

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